New Method for the Synthesis of Acetylacetone-Based closo-Borate Anion Derivatives [BnHn – 1NH=C(R)C(C(OH)CH3)C(O)CH3]–, Where n = 10, 12, R = Me, Et
The processes of nucleophilic addition of acetylacetone as a C-nucleophile to multiple bonds of nitrile derivatives of boron cluster anions have been studied in this work. The structures of the products have been established by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NH=C(C2H5)C(C(OH)CH3)C(O)CH3] has been established by single crystal X-ray analysis.
Authors
- К. Yu. Zhizhin (ORCID: https://orcid.org/0000-0002-4475-124X)
- А. V. Nelyubin (ORCID: https://orcid.org/0000-0002-9990-4231)
- Н. Т. Кузнецов (ORCID: https://orcid.org/0000-0002-2562-6427)
- Andrey P. Zhdanov (ORCID: https://orcid.org/0000-0003-4083-386X)
- Н. А. Селиванов (ORCID: https://orcid.org/0000-0001-7426-5982)
- A. Yu. Bykov (ORCID: https://orcid.org/0000-0003-1793-8487)
- I. N. Klyukin (ORCID: https://orcid.org/0000-0001-8940-3049)
- Alexey S. Kubasov (ORCID: https://orcid.org/0000-0002-0156-5535)
Institutions
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Publication Details
- Journal
- Russian Journal of Inorganic Chemistry
- Published
- 2024-10-01
- DOI
- https://doi.org/10.1134/s0036023624601910
- Primary Topic
- Boron Compounds in Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.00