High Volumetric and Gravimetric Acetylene Uptakes in a Cu-MOF with Tailored Cages
<b>NTUniv-80</b> exhibits record-high volumetric and gravimetric acetylene (C<sub>2</sub>H<sub>2</sub>) uptakes of 210 cm<sup>3</sup> (STP) g<sup>-1</sup> and 227 cm<sup>3</sup> (STP) cm<sup>-3</sup> at 295 K and 1 atm, respectively. Grand canonical Monte Carlo (GCMC) simulation indicates that those remarkable C<sub>2</sub>H<sub>2</sub> uptakes are attributed to the open Cu<sup>2+</sup> sites and tailored cages.
Authors
- Tony Pham (ORCID: https://orcid.org/0000-0001-5654-163X)
- Katherine A. Forrest (ORCID: https://orcid.org/0000-0002-5207-5739)
- Guoping Qin (ORCID: https://orcid.org/0000-0003-0007-4782)
- Xingge He (ORCID: https://orcid.org/0000-0001-9523-8780)
- Mingxing Zhang (ORCID: https://orcid.org/0000-0001-7904-461X)
- Miao Wang (ORCID: https://orcid.org/0000-0001-7390-2775)
- Tongming Sun
- Meng Chen (ORCID: https://orcid.org/0009-0002-5737-7573)
- Junyang Jiang
- Shangyu Wang
- Suer Guo
- Haitian Zhao (ORCID: https://orcid.org/0000-0003-3438-1991)
- Yu Wang (ORCID: https://orcid.org/0000-0002-8833-9564)
- Wei Wang (ORCID: https://orcid.org/0000-0002-9263-7927)
Institutions
- Chongqing Normal University (CN)
- North Carolina State University (US)
- Nantong University (CN)
- University of South Florida (US)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-10-28
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c02687
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Nantong University
- Natural Science Foundation of Chongqing
- Chongqing Municipal Education Commission
- Science and Technology Project of Nantong City