Synthesis and Characterization of Asymmetric Azatwistarenes with Chiroptical Property
Three novel azatwistarenes <b>5a</b>, <b>8</b>, and <b>13</b> have been synthesized via the Povarov reaction and fully characterized. All of the enantiomers were separated using chiral high-performance liquid chromatography, and their optical properties were investigated through circular dichroism and circularly polarized luminescence spectra. In addition, such desired azatwistarenes have a positive response to acid in dichloromethane.
Authors
- Jiawei Gao (ORCID: https://orcid.org/0000-0003-4432-1132)
- Jinchong Xiao (ORCID: https://orcid.org/0000-0002-5451-220X)
- Chengxiu Wang (ORCID: https://orcid.org/0000-0002-9583-239X)
- Yanjie Zhu
- Yanjun Deng
- Chunfang Zhang (ORCID: https://orcid.org/0000-0003-0768-0531)
- Hui Yang (ORCID: https://orcid.org/0000-0002-6745-642X)
- Guofeng Chen (ORCID: https://orcid.org/0000-0003-3321-5932)
Institutions
- Hebei University (CN)
Publication Details
- Journal
- Organic Letters
- Published
- 2024-10-28
- DOI
- https://doi.org/10.1021/acs.orglett.4c03442
- Citations
- 4
- Primary Topic
- Synthesis and Properties of Aromatic Compounds
- Type
- article
- Field-Weighted Citation Impact
- 1.00
Funders
- Natural Science Foundation of Hebei Province