Optimal control of port-Hamiltonian systems: Energy, entropy, and exergy

We consider irreversible and coupled reversible–irreversible nonlinear port-Hamiltonian systems and the respective sets of thermodynamic equilibria. In particular, we are concerned with optimal state transitions and output stabilization on finite-time horizons. We analyze a class of optimal control problems, where the performance functional can be interpreted as a linear combination of energy supply, entropy generation, or exergy supply. Our results establish the integral turnpike property towards the set of thermodynamic equilibria providing a rigorous connection of optimal system trajectories to optimal steady states. Throughout the paper, we illustrate our findings by means of two examples: a network of heat exchangers and a gas-piston system.