Synthesis mechanism of TiO₂ nanoparticles via high frequency electrical arc discharge

Abstract The rapid advancement of nanofabrication techniques has significantly increased the utilization of nanoparticles in recent years. This study investigates the synthesis of titanium dioxide (TiO 2 ) nanoparticles, highlighting their unique properties and diverse applications across scientific and industrial fields. These nanoparticles are valued for their biocompatibility and advantageous optical, electrical, and physical properties. Various synthesis methods—chemical, physical, and biological—are reviewed, with a particular focus on the electric arc discharge method. This method is distinguished by its efficiency and environmental friendliness, enabling the production of highly pure nanoparticles. Utilizing continuous and alternating sparks between two electrodes, the technique generates spherical nanoparticles with adjustable sizes, controlled by the energy of each spark. An RC circuit-based device was designed for this electrical discharge process. Dynamic light scattering (DLS) measurements revealed an average particle size of 164.51 nm with a standard deviation of 44.08 nm. Field emission scanning electron microscopy (FESEM) images showed both solid and hollow spherical TiO 2 nanoparticles. Energy dispersive spectroscopy (EDS) confirmed that the TiO 2 particles contained only titanium and oxygen, with no other elements detected. X-ray diffraction (XRD) analysis verified the crystal structure, predominantly identifying the anatase phase of the synthesized nanoparticles. This research enhances the understanding of TiO 2 nanoparticle synthesis and characterization, providing a foundation for future innovations in their extensive applications.