Quasiparticle spectroscopy in technologically relevant niobium using London penetration depth measurements: experiment and theory

Abstract The London penetration depth, <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>λ</mml:mi> <mml:mo stretchy="false">(</mml:mo> <mml:mi>T</mml:mi> <mml:mo stretchy="false">)</mml:mo> </mml:mrow> </mml:math> , was measured in various forms of niobium, including foils, thin films, single crystals, and samples from superconducting radio-frequency (SRF) cavities. We observed a significant difference in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>λ</mml:mi> <mml:mo stretchy="false">(</mml:mo> <mml:mi>T</mml:mi> <mml:mo stretchy="false">)</mml:mo> </mml:mrow> </mml:math> at low temperatures, <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>T</mml:mi> <mml:mo>&lt;</mml:mo> <mml:msub> <mml:mi>T</mml:mi> <mml:mrow> <mml:mi mathvariant="normal">c</mml:mi> </mml:mrow> </mml:msub> <mml:mrow> <mml:mo>/</mml:mo> </mml:mrow> <mml:mn>3</mml:mn> </mml:mrow> </mml:math> , due to low-energy quasiparticles. In particular, an unusual downturn of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>λ</mml:mi> <mml:mo stretchy="false">(</mml:mo> <mml:mi>T</mml:mi> <mml:mo stretchy="false">)</mml:mo> </mml:mrow> </mml:math> on cooling in the SRF cavity samples required to take into account deep in-gap bound states. Theoretical modeling using the generalized Dynes density of states shows that such in-gap states lead to a downturn or a peak in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" overflow="scroll"> <mml:mrow> <mml:mi>λ</mml:mi> <mml:mo stretchy="false">(</mml:mo> <mml:mi>T</mml:mi> <mml:mo stretchy="false">)</mml:mo> </mml:mrow> </mml:math> upon cooling. Combined, experimental and theoretical findings provide a method for detecting two-level systems or states related to magnetic impurities in the bulk of niobium. This result is particularly relevant for the quantum informatics sciences technologies used in qubits and circuit quantum electrodynamics architecture based on SRF cavities.