Metalloporphyrinic metal–organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant
Four metalloporphyrinic metal-organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH<sub>2</sub>(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.
Authors
- Long Hao Qi (ORCID: https://orcid.org/0000-0002-1213-2946)
- Omar K. Farha (ORCID: https://orcid.org/0000-0002-9904-9845)
- Edgar K. Papazyan (ORCID: https://orcid.org/0000-0002-4959-1302)
- Anna Nguyen (ORCID: https://orcid.org/0000-0001-9004-2092)
- Pavithra Wijeratne (ORCID: https://orcid.org/0000-0001-5805-0818)
- Austin D. Ready (ORCID: https://orcid.org/0000-0001-8051-7568)
- Lun An (ORCID: https://orcid.org/0000-0003-2146-1490)
- Alisa S. Quon (ORCID: https://orcid.org/0009-0000-5167-9891)
- Yangyang Liu (ORCID: https://orcid.org/0000-0002-3913-5979)
- Mei San Tang (ORCID: https://orcid.org/0000-0003-2589-3477)
- Doroteo Manriquez
Institutions
- Northwestern University (US)
- University of California, Los Angeles (US)
- Iowa State University (US)
- California State University Los Angeles (US)
- Ames National Laboratory (US)
- International Institute for Nanotechnology
Publication Details
- Journal
- Chemical Communications
- Published
- 2024-10-28
- DOI
- https://doi.org/10.1039/d4cc03890h
- Citations
- 11
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 1.74
Funders
- National Science Foundation
- U.S. Department of Energy
- Iowa State University
- National Institutes of Health
- Basic Energy Sciences
- Core Research for Evolutional Science and Technology
- Army Research Office