Recyclable Ag/g‐C₃N₄ Catalyzed Visible‐light Promoted Heterogeneous Synthesis of Unsymmetric Diaryl Chalcogenides

Abstract With Ag/g‐C 3 N 4 semiconductor as the heterogeneous photocatalyst, the visible light promoted heterogeneous synthesis of unsymmetric diaryl chalcogenides could be achieved under additive‐free and mild conditions. A series of unsymmetric diaryl chalcogenides were generated in good to excellent yields with high functional group tolerance. The Ag/g‐C 3 N 4 photocatalyst is easily recovered from the reaction mixture and reused at least 5 times, opening the way for larger‐scale industrial applications of this type of photocatalytic bond‐forming reactions.