Transparent and Thermally Stable Rare-Earth-Doped Luminescent Gallate Glass toward Passive Daytime Radiative Cooling Applications

Currently, the implementation of passive daytime radiative cooling based on zero-energy cooling methodologies primarily focuses on polymers and composite materials, whereas the available literature on all-inorganic materials is relatively few. Here, we present a novel microcrystalline glass material CaGa_0.5Al_1.5O₄ (CGAO), doped with rare-earth elements and prepared by the high-temperature melting method. This material exhibits long-term stability at 200 °C, coupled with an effective infrared radiation cooling function, demonstrating a 4.9 °C temperature reduction at solar noon. The energy transfer and luminescence mechanisms of Tb³⁺ and Sm³⁺ doped CGAO glass have been thoroughly investigated, along with thorough assessments of its thermal stability and hardness. The glass exhibits ultrahigh light transmission in the ultraviolet to near-infrared range, with the transmittance reaching 98% in specific spectral bands. Furthermore, it demonstrates superior luminescent thermal stability, retaining 85.6% and 71.2% of its initial luminescence intensity at 423 and 523 K, respectively. The high-temperature resistance and stability and long-term cooling properties render CGAO glass as an optimal candidate for integration into future energy-efficient and sustainable building designs.