On Specific Quenching of Tb<sup>3+</sup> Ions Radioluminescence in Aqueous Solutions by Hydrogen Atom

The influence of acceptors of the water radiolysis primary products of the H atom and ea–q on the spectra and intensity of the Tb3+ ion radioluminescence and photoluminescence in aqueous solutions of TbCl3 and Tb(NO3)3 is considered. The activation effect of Tb3+ radioluminescence in the presence of H acceptors was revealed, indicating the presence of a specific quenching reaction (Tb3+)* by this radiolysis product, inhibited by its acceptors. An increase in activation was found in the joint presence of H and hydrated electron acceptors in the solution; for acceptors of the latter, a similar activation effect of Tb3+ radioluminescence was established earlier.

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Publication Details

Journal
Химия высоких энергий
Published
2024-10-25
DOI
https://doi.org/10.31857/s0023119324030049
Primary Topic
Luminescence Properties of Advanced Materials
Type
article
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article

On Specific Quenching of Tb3+ Ions Radioluminescence in Aqueous Solutions by Hydrogen Atom

L. R. Yakshembetova, Г. Л. Шарипов, А. М. Абдрахманов, Б. М. Гареев
Химия высоких энергий
Luminescence Properties of Advanced Materials
article

On Specific Quenching of Tb3+ Ions Radioluminescence in Aqueous Solutions by Hydrogen Atom

L. R. Yakshembetova, Г. Л. Шарипов, А. М. Абдрахманов, Б. М. Гареев
article en

Abstract

The influence of acceptors of the water radiolysis primary products of the H atom and ea–q on the spectra and intensity of the Tb3+ ion radioluminescence and photoluminescence in aqueous solutions of TbCl3 and Tb(NO3)3 is considered. The activation effect of Tb3+ radioluminescence in the presence of H acceptors was revealed, indicating the presence of a specific quenching reaction (Tb3+)* by this radiolysis product, inhibited by its acceptors. An increase in activation was found in the joint presence of H and hydrated electron acceptors in the solution; for acceptors of the latter, a similar activation effect of Tb3+ radioluminescence was established earlier.

Химия высоких энергийVol. 58(3)
Ufa Institute of Chemistry (RU)
Openalex Percentile: Top 88%
Luminescence Properties of Advanced Materials
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