Eco-friendly anaerobic oxidation of aryl diazo esters with heterocyclic <i>N</i>-oxide under ball milling: synthesis of 1,2-dicarbonyl systems

Herein we report anaerobic oxidation of metal carbenoids generated from aryl diazo esters under ball milling with heterocyclic N -oxide in the presence of catalytic copper( i ) to afford 1,2-dicarbonyls in excellent yield.

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Publication Details

Journal
RSC Mechanochemistry
Published
2024-10-25
DOI
https://doi.org/10.1039/d4mr00097h
Citations
4
Primary Topic
Chemical Reactions and Isotopes
Type
article
Field-Weighted Citation Impact
0.83

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article

Eco-friendly anaerobic oxidation of aryl diazo esters with heterocyclic N-oxide under ball milling: synthesis of 1,2-dicarbonyl systems

Subhabrata Sen, Souvik Guha, Ludovic Gremaud
4 citations
RSC Mechanochemistry
Chemical Reactions and Isotopes
0.83
article

Eco-friendly anaerobic oxidation of aryl diazo esters with heterocyclic N-oxide under ball milling: synthesis of 1,2-dicarbonyl systems

Subhabrata Sen, Souvik Guha, Ludovic Gremaud
article en
4 citations

Abstract

Herein we report anaerobic oxidation of metal carbenoids generated from aryl diazo esters under ball milling with heterocyclic N -oxide in the presence of catalytic copper( i ) to afford 1,2-dicarbonyls in excellent yield.

RSC MechanochemistryVol. 2(1)
Shiv Nadar University (IN), School of Engineering and Architecture of Fribourg (CH), HES-SO Fribourg (CH)
Haute école Spécialisée de Suisse Occidentale, Zürcher Hochschule für Angewandte Wissenschaften
Openalex Percentile: Top 31%
Chemical Reactions and Isotopes
0.83
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