Crystal structure of <i>N</i>,<i>N</i>′,<i>N</i>′′-tricyclopropylbenzene-1,3,5-tricarboxamide
The title compound, C<sub>18</sub>H<sub>21</sub>N<sub>3</sub>O<sub>3</sub>, was prepared from 1,3,5-benzene-tricarbonyl trichloride and cyclo-propyl-amine. Its crystal structure was solved in the monoclinic space group <i>P</i>2<sub>1</sub>/<i>c</i>. In the crystal, the three amide groups of the mol-ecule are inclined at angles of 26.5 (1), 36.9 (1) and 37.8 (1)° with respect to the plane of the benzene ring. The mol-ecules are linked by N-H⋯O hydrogen bonds, forming two-dimensional supra-molecular aggregates that extend parallel to the crystallographic <i>ab</i> plane and are further connected by C-H⋯O contacts. As a result of the supra-molecular inter-actions, a propeller-like conformation of the title mol-ecule can be observed.
Authors
- Manuel Stapf (ORCID: https://orcid.org/0000-0001-6398-2337)
- Monika Mazik (ORCID: https://orcid.org/0000-0003-3571-7899)
- Venugopal Rao Miyyapuram
- Wilhelm Seichter
Institutions
- Fisher Bioservices (United States) (US)
- Thermo Fisher Scientific (United States) (US)
- TU Bergakademie Freiberg (DE)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2024-10-24
- DOI
- https://doi.org/10.1107/s2056989024009800
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00