Increasingly threaded polypseudorotaxanes with reduced enthalpies of melting
We used acyclic diene metathesis (ADMET) chemistry to prepare variably threaded pseudopolyrotaxanes. We find that the melting enthalpy decreases as the number density of macrocycles is increased.
Authors
- J. Marquez (ORCID: https://orcid.org/0000-0003-3887-4048)
- Sean R. Gitter (ORCID: https://orcid.org/0000-0003-2426-5321)
- Kenneth B. Wagener (ORCID: https://orcid.org/0000-0001-9542-0259)
- Brent S. Sumerlin (ORCID: https://orcid.org/0000-0001-5749-5444)
- Austin M. Evans (ORCID: https://orcid.org/0000-0002-3597-2454)
- Kiana A. Treaster (ORCID: https://orcid.org/0009-0003-3273-0403)
- He Sun (ORCID: https://orcid.org/0000-0003-3461-8426)
Institutions
- University of Florida (US)
Publication Details
- Journal
- Polymer Chemistry
- Published
- 2024-10-24
- DOI
- https://doi.org/10.1039/d4py01006j
- Citations
- 1
- Primary Topic
- Silicone and Siloxane Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.12