Organic Photoredox-Catalyzed Hydrosilylation of Vinylboronic Esters for the Synthesis of Geminal and Vicinal Borosilanes
Geminal and vicinal borosilanes have unique applications in functional materials and synthetic transformations. Herein, a convenient method for the synthesis of geminal and vicinal borosilanes is developed via photoredox metal-free hydrosilylation of vinylboronic esters. This strategy features the advantages of high atom economy, environmental friendliness, and excellent functional group compatibility. The mechanism studies reveal that the catalytic reaction goes through photoredox HAT catalysis and a radical addition pathway.
Authors
- Pan Han (ORCID: https://orcid.org/0000-0002-5567-9693)
- Lin‐Hai Jing (ORCID: https://orcid.org/0000-0001-6424-4491)
- Zhengbing Zhang (ORCID: https://orcid.org/0000-0001-7458-4465)
- Yue Zhang (ORCID: https://orcid.org/0000-0002-8173-9696)
- Yuanyuan Liu (ORCID: https://orcid.org/0000-0001-9865-1378)
- Ting Wang (ORCID: https://orcid.org/0000-0001-7630-4148)
Institutions
- China West Normal University (CN)
Publication Details
- Journal
- The Journal of Organic Chemistry
- Published
- 2024-10-24
- DOI
- https://doi.org/10.1021/acs.joc.4c01731
- Citations
- 4
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 1.00
Funders
- National Natural Science Foundation of China
- Department of Science and Technology of Sichuan Province
- China West Normal University