Adsorption and Permeation Events in Molecular Diffusion

How many times can a diffusing molecule permeate across a membrane or be adsorbed on a substrate? We employ an encounter-based approach to find the statistics of adsorption or permeation events for molecular diffusion in a general confining medium. Various features of these statistics are illustrated for two practically relevant cases: a flat boundary and a spherical confinement. Some applications of these fundamental results are discussed.

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Publication Details

Journal
Molecules
Published
2024-10-23
DOI
https://doi.org/10.3390/molecules29215012
Citations
1
Primary Topic
Diffusion and Search Dynamics
Type
article
Field-Weighted Citation Impact
0.23

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article

Adsorption and Permeation Events in Molecular Diffusion

Denis S. Grebenkov
1 citations
Molecules
Diffusion and Search Dynamics
0.23
article

Adsorption and Permeation Events in Molecular Diffusion

Denis S. Grebenkov
article en
1 citations

Abstract

How many times can a diffusing molecule permeate across a membrane or be adsorbed on a substrate? We employ an encounter-based approach to find the statistics of adsorption or permeation events for molecular diffusion in a general confining medium. Various features of these statistics are illustrated for two practically relevant cases: a flat boundary and a spherical confinement. Some applications of these fundamental results are discussed.

MoleculesVol. 29(21)
Centre National de la Recherche Scientifique (FR), École Polytechnique (FR), Université de Montréal (CA)
Alexander von Humboldt-Stiftung
Openalex Percentile: Top 42%
Diffusion and Search Dynamics
0.23
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