Flowerlike Spreading of Micellar Films during Emulsion Drop Evaporation

We investigated the film spreading during the evaporation of submillimeter oil-in-water emulsion droplets on a solid surface, and observed a novel phenomenon where the film follows a two-layer spreading. In combination with the instability at the film front, the spreading front acquires a flowerlike pattern. The emergence of the two-layer structure is attributed to micelles within the oil film that yield an oscillating disjoining pressure. By considering both the slipping condition and the disjoining pressure, a scaling analysis is carried out that agrees well with the observed film spreading dynamics. The film spreading follows Tanner's law initially, while it becomes faster at a later stage, where the film radius follows r∼t^{1/2} for weak slip and r∼t^{3/8} for strong slip conditions.