Time-convolutionless master equation applied to adiabatic elimination

In open quantum systems theory, reduced models are invaluable for conceptual understanding and computational efficiency. Adiabatic elimination is a useful model reduction method for systems with separated timescales, where a reduced model is derived by discarding rapidly decaying degrees of freedom. So far, adiabatic elimination has been formulated using a geometric approach, which provides a versatile and general framework. This article introduces a reformulation of adiabatic elimination through the framework of the time-convolutionless (TCL) master equation, a widely recognized tool for computing projected time evolution in open quantum systems. We show that the TCL master equation formulation yields results equivalent to those obtained from the geometric formulation. By applying the TCL master equation formulation to typical examples, we demonstrate a practical methodology for performing adiabatic elimination calculation. This study not only bridges two previously independent approaches, thereby making the adiabatic elimination method accessible to a broader audience, but also enables the analysis of complex cases that are challenging within the geometric formulation. Additionally, it reveals a geometric interpretation of the TCL master equation formalism.

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Publication Details

Journal
Physical review. A/Physical review, A
Published
2025-05-08
DOI
https://doi.org/10.1103/physreva.111.052206
Citations
2
Primary Topic
Spectroscopy and Quantum Chemical Studies
Type
article
Field-Weighted Citation Impact
2.49

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article

Time-convolutionless master equation applied to adiabatic elimination

Masaaki Tokieda, Angela Riva
2 citations
Physical review. A/Physical review, A
Spectroscopy and Quantum Chemical Studies
2.49
article

Time-convolutionless master equation applied to adiabatic elimination

Masaaki Tokieda, Angela Riva
article en
2 citations

Abstract

In open quantum systems theory, reduced models are invaluable for conceptual understanding and computational efficiency. Adiabatic elimination is a useful model reduction method for systems with separated timescales, where a reduced model is derived by discarding rapidly decaying degrees of freedom. So far, adiabatic elimination has been formulated using a geometric approach, which provides a versatile and general framework. This article introduces a reformulation of adiabatic elimination through the framework of the time-convolutionless (TCL) master equation, a widely recognized tool for computing projected time evolution in open quantum systems. We show that the TCL master equation formulation yields results equivalent to those obtained from the geometric formulation. By applying the TCL master equation formulation to typical examples, we demonstrate a practical methodology for performing adiabatic elimination calculation. This study not only bridges two previously independent approaches, thereby making the adiabatic elimination method accessible to a broader audience, but also enables the analysis of complex cases that are challenging within the geometric formulation. Additionally, it reveals a geometric interpretation of the TCL master equation formalism.

Physical review. A/Physical review, AVol. 111(5)
Institut national de recherche en sciences et technologies du numérique (FR), Kyoto University (JP), Sorbonne Université (FR), École Normale Supérieure (BI), Laboratoire Médiations (FR), École Nationale Supérieure des Mines de Paris (FR)
Agence Nationale de la Recherche, Japan Society for the Promotion of Science
Peace, Justice and strong institutions
Openalex Percentile: Top 14%
Spectroscopy and Quantum Chemical Studies
2.49
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Time-convolutionless master equation applied to adiabatic elimination — Masaaki Tokieda, Angela Riva · Physical review. A/Physical review, A (2025) | TGRS Research Map | TGRS