Pyrolysis models for pressure treated wood and wood–plastic composite

Abstract Pressure treated wood (PTW) and wood–plastic composites such as Trex® are popular materials for the construction of decks and other auxiliary structures, which are known to significantly contribute to spread of wildland fires into communities. In this work, representative samples of these materials were studied to determine their pyrolysis and combustion properties to enable simulation of fire growth on the surface of these building products. The pyrolysis property development process followed a well‐established hierarchical approach where thermogravimetric analysis, differential scanning calorimetry, and microscale combustion calorimetry were used to parametrize kinetics and thermodynamics of the thermal decomposition and combustion, while controlled atmosphere pyrolysis and cone calorimetry tests performed on coupon‐sized samples were used to parameterize thermal transport properties and validate performance of the fully parametrized pyrolysis models. PTW decomposition was captured using four sequential reactions with one additional reaction used to model vaporization of water. Trex® board was found to consist of two distinct layers: a thin outer layer and an internal core. The pyrolysis model for this material was constructed using some known properties of high‐density polyethylene (PE) and the properties of PTW determined in this work. The outer layer was defined in the model to consist of PE and an inert additive, while the core was defined as a blend of PE and wood particles, which kinetics and thermodynamics of the thermal decomposition and combustion were successfully captured using the model developed for PTW.