Synthesis, Structure, and Bonding of Actinide–Rhenium Polyhydrides
The synthesis of actinide tetrarhenate complexes completes a series of iridate, osmate, and rhenate polyhydrides, allowing for structural and bonding comparisons to be made. Computational studies examine the bonding interactions, particularly between metals, in these complexes. Several factors─including metal oxidation state, coordination number, and dispersion effects─affect metal-metal distances and covalency in these actinide tetrametallates. Related osmium and rhenium octametallic U<sub>2</sub>M<sub>6</sub> clusters are synthesized and described, and subjected to similar structural and electronic analyses.
Authors
- John Arnold (ORCID: https://orcid.org/0000-0001-9671-227X)
- Erik T. Ouellette (ORCID: https://orcid.org/0000-0003-2138-6259)
- Christopher Z. Ye (ORCID: https://orcid.org/0000-0001-5260-1113)
- Sheridon N. Kelly (ORCID: https://orcid.org/0000-0003-0999-6919)
- Iker Del Rosal (ORCID: https://orcid.org/0000-0001-6898-4550)
- Clément Camp (ORCID: https://orcid.org/0000-0001-8528-0731)
- Laurent Maron (ORCID: https://orcid.org/0000-0003-2653-8557)
Institutions
- Université Claude Bernard Lyon 1 (FR)
- Centre National de la Recherche Scientifique (FR)
- Lawrence Berkeley National Laboratory (US)
- Université Fédérale de Toulouse Midi-Pyrénées (FR)
- Institut National des Sciences Appliquées de Toulouse (FR)
- University of California System (US)
- Institut de Chimie (FR)
- Laboratoire de Physique et Chimie des Nano-Objets (FR)
- École d'Ingénieurs en Chimie et Sciences du Numérique (FR)
- University of California, Berkeley (US)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-10-22
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c03449
- Citations
- 2
- Primary Topic
- Inorganic Chemistry and Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.32
Funders
- Centre National de la Recherche Scientifique
- Basic Energy Sciences