(R)-3,3,6-Trimethyl-3,3a,4,5-tetrahydro-1H-cyclopenta[c]furan
(R)-3,3,6-trimethyl-3,3a,4,5-tetrahydro-1H-cyclopenta[c]furan was obtained by the acid cyclization of the alcohol (S)-(2-methyl-5-(prop-1-en-2-yl)cyclopent-1-en-1-yl)methanol, which, in turn, is obtained from (R)-limonene. The structure of the new compound was established using NMR spectroscopy (1H, 13C, COSY, HSQC, and HMBC spectra) and high-resolution mass spectrometry. The chemical shifts of the proton and carbon atoms were calculated at the DFT level with a high correlation between the calculated and experimental values.
Authors
- J. Antonio Palenzuela (ORCID: https://orcid.org/0000-0001-9629-5285)
- Marı́a M. Afonso (ORCID: https://orcid.org/0000-0003-3186-6870)
- J. Rodriguez (ORCID: https://orcid.org/0000-0002-2488-5494)
- Débora María Marichal-Medina
Institutions
- Universidad de La Laguna (ES)
Publication Details
- Journal
- Molbank
- Published
- 2024-10-21
- DOI
- https://doi.org/10.3390/m1902
- Primary Topic
- Asymmetric Synthesis and Catalysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00