Lewis acid-controlled Pd-catalyzed chemodivergent hydrocyanation of cyclopropenes
We report a Lewis acid-controlled Pd-catalyzed chemodivergent hydrocyanation of cyclopropenes. In the absence of Al Lewis acid, the reaction predominantly yields ring-opened allylic nitrile products while the addition of Lewis acid favors the formation of cyano-substituted cyclopropane products.
Authors
- Song‐Zhou Cai
- Xianjie Fang (ORCID: https://orcid.org/0000-0002-3471-8171)
- Rongrong Yu (ORCID: https://orcid.org/0009-0003-4020-1720)
Institutions
- Hangzhou Normal University (CN)
- Shanghai Jiao Tong University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-10-22
- DOI
- https://doi.org/10.1039/d4qo01609b
- Citations
- 5
- Primary Topic
- Cyclopropane Reaction Mechanisms
- Type
- article
- Field-Weighted Citation Impact
- 1.25