Kill Two Birds with One Stone: Cracking Lithography Technology for High-Performance Flexible Metallic Network Transparent Conductors and Metallic Micronano Sheets

Flexible electronics have sparked a wide range of exciting applications, such as flexible display technologies, lighting, sensing, etc. Flexible conductors are essential components of flexible electronics and seriously affect efficiency and overall performance. Here, a facile and kill-two-birds-with-one-stone strategy of cracking lithography technology has been proposed to simultaneously fabricate two high-performance flexible conductors, flexible metallic network transparent conductors (<i>f</i>-NTCs) and metallic micronano sheets (MMNSs). The PET substrate flexible transparent conductors (FTCs) based on this strategy yield 88.1% transparency within the visible spectrum and a sheet resistance of 9 Ω/sq. In addition, the FTCs show exceptional mechanical stability, with the sheet resistance remaining virtually unchanged even after 6000 s of bending tests. Subsequently, the remaining MMNSs are recycled to manufacture a Ag paste, showing a very low conductive percolation threshold (∼13%) and excellent flexibility with 140% breaking elongation. After 1000 s of stretching tests, it showed excellent mechanical stability. Furthermore, flexible electroluminescent devices based on the FTCs and sensors fabricated with MMNSs both show excellent performance, demonstrating their potential wide applications in flexible electronics.