Energetic Salts of Cubane-1,4-Dimethylnitrocarbamate
Several salts of cubane-1,4-dimethylnitrocarbamate (CMNC) were synthesized. The divalent CMNC is deprotonated by alkaline, alkaline earth metal, and nonmetal bases to form the corresponding salts. The compounds were characterized and analyzed by multinuclear NMR and IR spectroscopy, mass spectrometry, elemental analysis, single crystal X-ray, and thermoanalytical techniques. The energies of formation for the salts were calculated using Gaussian. Detonation performances were calculated with the Explo5 (V6.03) computer code. The sensitivities toward impact and friction were determined and compared to the neutral CMNC.
Authors
- Burkhard Krumm (ORCID: https://orcid.org/0000-0002-2100-4540)
- Thomas M. Klapoetke (ORCID: https://orcid.org/0000-0003-3276-1157)
- Andreas Bartonek (ORCID: https://orcid.org/0009-0008-4614-4989)
Institutions
- Ludwig-Maximilians-Universität München (DE)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2024-10-19
- DOI
- https://doi.org/10.1021/acs.inorgchem.4c03665
- Citations
- 2
- Primary Topic
- Energetic Materials and Combustion
- Type
- article
- Field-Weighted Citation Impact
- 0.54
Funders
- Ludwig-Maximilians-Universität München
- Strategic Environmental Research and Development Program
- Office of Naval Research