Stability of Supramolecular β-Cyclodextrin-Pyrene Complexes in A Silicate Hydrogel Matrix

In order to use the β-cyclodextrin-pyrene complex as a fluorescent receptor center, its stability in the solid phase of a water-soluble silicate gel was investigated. For this purpose, a technique for obtaining a silicate matrix with a high content of supramolecular complexes was developed and the temperature stability of the resulting material was investigated. Optimal conditions for working with complexes in the silica gel matrix have been identified. Comparative studies of the fluorescence spectra of complexes in liquid and solid phases were carried out by the method of fluorescence spectroscopy. As a result of the work done, it was possible to determine the main patterns of behavior of the supramolecular complex in the silicate hydrogel matrix and to conclude about the influence of the matrix structure on its stability.

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Publication Details

Journal
Журнал неорганической химии
Published
2024-10-19
DOI
https://doi.org/10.31857/s0044457x24040122
Primary Topic
Analytical Chemistry and Chromatography
Type
article
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article

Stability of Supramolecular β-Cyclodextrin-Pyrene Complexes in A Silicate Hydrogel Matrix

А. A. Medvedeva, A. V. Koshkin, A. V. Kondakova
Журнал неорганической химии
Analytical Chemistry and Chromatography
article

Stability of Supramolecular β-Cyclodextrin-Pyrene Complexes in A Silicate Hydrogel Matrix

А. A. Medvedeva, A. V. Koshkin, A. V. Kondakova
article en

Abstract

In order to use the β-cyclodextrin-pyrene complex as a fluorescent receptor center, its stability in the solid phase of a water-soluble silicate gel was investigated. For this purpose, a technique for obtaining a silicate matrix with a high content of supramolecular complexes was developed and the temperature stability of the resulting material was investigated. Optimal conditions for working with complexes in the silica gel matrix have been identified. Comparative studies of the fluorescence spectra of complexes in liquid and solid phases were carried out by the method of fluorescence spectroscopy. As a result of the work done, it was possible to determine the main patterns of behavior of the supramolecular complex in the silicate hydrogel matrix and to conclude about the influence of the matrix structure on its stability.

Журнал неорганической химииVol. 69(4)
Photochemistry Center (RU)
Openalex Percentile: Top 86%
Analytical Chemistry and Chromatography
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Stability of Supramolecular β-Cyclodextrin-Pyrene Complexes in A Silicate Hydrogel Matrix — А. A. Medvedeva, A. V. Koshkin, et al. · Журнал неорганической химии (2024) | TGRS Research Map | TGRS