Unravelling the different pathways of cyclohexene oxidation <i>via</i> a peroxyl radical generated from <i>tert</i>-butyl hydroperoxide (TBHP) by various metal salts
Two different mechanisms were obtained in the selective oxidation of cyclohexene catalyzed by CuCl 2 and VCl 3 respectively in presence of TBHP. The two opposed mechanisms are mainly caused by the roles of the t -BuOO˙ radical in catalytic oxidations.
Authors
- Xiantai Zhou (ORCID: https://orcid.org/0000-0003-4918-4421)
- Can Xue (ORCID: https://orcid.org/0000-0002-2425-7922)
- Hanwen Zhang (ORCID: https://orcid.org/0000-0003-0766-1816)
- Xiaohui Liu (ORCID: https://orcid.org/0000-0002-2693-4827)
- Lei Zhou (ORCID: https://orcid.org/0000-0001-5893-6002)
- Han-Kang Zhong
Institutions
- Sun Yat-sen University (CN)
- Huizhou University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-10-18
- DOI
- https://doi.org/10.1039/d4qo01681e
- Citations
- 6
- Primary Topic
- Oxidative Organic Chemistry Reactions
- Type
- article
- Field-Weighted Citation Impact
- 1.50