Groundwater renewal time by environmental tritium isotopes as a tracer for sustainable water resource management

Studying groundwater renewal time is a valuable tool to deepen the comprehension of sustainable groundwater resources specific to arid regions. Tritium is a radioactive isotope of hydrogen often used as an environmental tracer to study groundwater renewal time. The present work reports groundwater renewal times by the environmental tracer tritium to understand sustainable water resources in arid regions. First, groundwater samples were collected from wells in northeastern arid regions of Saudi Arabia. Then, an electrolysis process was employed to significantly increase the tritium level from twenty-five to thirty times the original concentration. Subsequently, the enriched water was analyzed using a liquid scintillation counter under optimized measurement conditions to determine the tritium concentration precisely. Two internationally recognized tritium laboratories conducted independent assessments to validate the estimated tritium levels. The verified tritium concentration was then used to estimate the groundwater renewal time using the Morgenstern and Pimenta curves. The results suggest that most of the monitored wells in the surveyed areas are more than a century old. Conversely, a few monitoring wells exhibit renewal times of several hundred years and may be considered nonrenewable water sources. These studies help to understand the geochemical characteristics of arid regions to ensure the sustainable management and protection of groundwater resources.