Measurement report: Intra-annual variability of black carbon and brown carbon and their interrelation with meteorological conditions over Gangtok, Sikkim

Abstract. Black carbon (BC) and brown carbon (BrC) both have a versatile nature, and they have an apparent role in climate variability and changes. As anthropogenic activity is surging, BC and BrC are also reportedly increasing. So, the monitoring of BC and BrC and observations of land use land cover change (LULCC) at a regional level are necessary for the changes in various interconnected meteorological phenomena. The current study investigates BC, BrC, CO2, BC from fossil fuels (BCff), BC from biomass burning (BCbb), and LULCC and their relationship to the corresponding meteorological conditions over Gangtok in the Sikkim Himalayan region. The concentration of BC (BrC) was found to be highest during March 2022 (April 2021) at 43.5 µg m−3 (32.0 µg m−3)​​​​​​​. Surface pressure exhibits a significant positive correlation with BC, BCff, BCbb, and BrC. Higher surface pressure results in a calmer and more stable boundary layer, which effectively retains deposited contaminants. Conversely, the wind appears to facilitate the dispersion of pollutants, showing a strong negative correlation. The fact that all pollutants and precipitation have been shown to behave similarly points to moist scavenging of the pollutants. Despite the dense cloud cover, it is clear that the area is not receiving convective precipitation, implying that orographic precipitation is occurring over the region. Most of Sikkim receives convective rain from May to September, indicating that the region has significant convective activity contributed from the Bay of Bengal during the monsoon season. Furthermore, monsoon months have the lowest concentrations of BC, BCbb, BCff, and BrC, suggesting the potential of convective rain (as rainout scavenging) to remove most of the pollutants.