High Specific Surface Area 2D/1D Hybrid Materials of Nb₂CT_<i>x</i>/CNT for Efficient VOCs Detection at Room Temperature

Monitoring of volatile organic compounds (VOCs) is important in many fields. MXene, a class of two-dimensional materials, exhibits significant potential for high-sensitivity VOCs detection owing to its high specific surface area and abundant functional groups. However, MXene layers tend to restack or aggregate in practical applications due to van der Waals forces and hydrogen bonding, which leads to a decrease of surface area compared to theoretical performance. One-dimensional (1D) carbon nanotube (CNT)/two-dimensional (2D) MXene mixed-dimensional heterostructures have been proven to be effective in improving catalytic efficiency or battery performance. Therefore, in this study, CNT and MXene (Nb2CTx) are constructed as hybrids, which effectively reduced the restack of MXene layers, thereby increasing the surface area available for VOCs binding. The sensitivity of the hybrids to ethanol and acetone is 3.9 and 5.6 times higher than that of pristine Nb2CTx, respectively. In addition, the sensor based on Nb2CTx/CNT hybrids shows a higher response to a variety of VOCs and exhibits good stability. It is an effective method for VOCs detection to take advantage of the high specific surface area of low-dimensional materials by constructing mixed-dimensional heterostructures.