Modification of the Activities of Components in Ca<sub>2</sub>SiO<sub>4</sub>–Ca<sub>3</sub>P<sub>2</sub>O<sub>8</sub> Solid Solution at 1573 K

The activities of components in Ca2SiO4–Ca3P2O8 solid solutions have been reported by preceding studies as the basic thermodynamic data for phosphorus removal in the steelmaking process. Since the reported activities contained the uncertainties accumulated from thermodynamic data, this study aimed to reevaluate the experimental results in the preceding studies. Firstly, the equilibrium constant of the following reaction used to calculate the P2O5 activities was measured at 1573 K through a gas equilibrium method.

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Publication Details

Journal
ISIJ International
Published
2024-10-16
DOI
https://doi.org/10.2355/isijinternational.isijint-2024-243
Citations
1
Primary Topic
Solid-state spectroscopy and crystallography
Type
article
Field-Weighted Citation Impact
0.12

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article

Modification of the Activities of Components in Ca2SiO4–Ca3P2O8 Solid Solution at 1573 K

Keijiro Saito, M. Hasegawa
1 citations
ISIJ International
Solid-state spectroscopy and crystallography
0.12
article

Modification of the Activities of Components in Ca2SiO4–Ca3P2O8 Solid Solution at 1573 K

Keijiro Saito, M. Hasegawa
article en
1 citations

Abstract

The activities of components in Ca2SiO4–Ca3P2O8 solid solutions have been reported by preceding studies as the basic thermodynamic data for phosphorus removal in the steelmaking process. Since the reported activities contained the uncertainties accumulated from thermodynamic data, this study aimed to reevaluate the experimental results in the preceding studies. Firstly, the equilibrium constant of the following reaction used to calculate the P2O5 activities was measured at 1573 K through a gas equilibrium method.

ISIJ InternationalVol. 64(15)
Kyoto University (JP)
University of Tokyo, Japan Society for the Promotion of Science
Industry, innovation and infrastructure
Openalex Percentile: Top 59%
Solid-state spectroscopy and crystallography
0.12
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