Phosphorous Doped Graphitic Carbon Nitride (P‐g‐C₃N₄) as an Electrochemical Platform for the Simultaneous Detection of Xanthine and Caffeine

Abstract A one step strategy was employed for the preparation of phosphorous doped g‐C 3 N 4 (P‐g‐C 3 N 4 ) using melamine phosphate. Herein, the precursor upon thermal condensation at 550 °C resulted in the formation of P‐g‐C 3 N 4 nanosheets. The as‐synthesised P‐g‐C 3 N 4 nanosheets were characterized by UV‐vis, FT‐IR and Raman spectroscopy. Later, surface morphological analysis were carried out using FESEM and HRTEM. Moreover, the crystalline nature and elemental composition analysis were conducted using XRD and XPS. Following this, P‐g‐C 3 N 4 nanosheets modified glassy carbon (GC) electrode was employed for the simultaneous detection of xanthene and caffeine. The modified electrode was found to be linear in the range of 0.1 to 100 μM (for xanthine) and 0.05 to 100 μM (for caffeine). The limit of detection was found to be 10 nM and 14 nM for xanthine and caffeine respectively. Further, the electrode exhibited a highly selective detection towards each of these analyte when they co‐exists.