General ppm-level Pd-catalysed asymmetric diarylalkyne hydrosilylation to access structurally diverse Si-stereogenic vinylsilanes
The first example of enantioselective Pd-catalyzed hydrosilylation of symmetric and asymmetric diarylalkynes to access novel Si-stereogenic vinylsilanes with excellent ee and a high TON is realized under mild reaction conditions.
Authors
- Li‐Wen Xu (ORCID: https://orcid.org/0000-0001-5705-0015)
- Heng Xu (ORCID: https://orcid.org/0000-0002-0929-6253)
- Liqing Li (ORCID: https://orcid.org/0000-0001-8297-309X)
- Fuk Yee Kwong (ORCID: https://orcid.org/0000-0001-9105-1740)
- Fei Ye (ORCID: https://orcid.org/0000-0002-4368-0267)
- Hong Yu (ORCID: https://orcid.org/0000-0003-4673-5734)
- Fu‐Tyan Lin
- An‐Jiu Wen
Institutions
- Hangzhou Normal University (CN)
- Chinese University of Hong Kong, Shenzhen (CN)
- State Key Laboratory of Synthetic Chemistry (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2024-10-16
- DOI
- https://doi.org/10.1039/d4qo01698j
- Citations
- 9
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 2.25