Self-Repairable Carbon Fiber-Reinforced Epoxy Vitrimer Actuator with Multistimulus Responses and Programmable Morphing

Smart shape-changing structures in aerospace applications are vulnerable to damage in harsh environments. Balancing high mechanical performance with self-repair capabilities poses a challenge due to inherent trade-offs between strength and flexibility. To address this challenge, an asymmetric bilayer-structured actuator was fabricated using commercially available continuous carbon fiber tows (CFs) as the passive layer and a dynamic cross-linked epoxy vitrimer as the active layer. The construction of the vitrimer-CF actuator involves a simple and scalable hot-pressing process, resulting in a tensile strength of 234 MPa and an interfacial bonding strength of 405 N·m^-1. This actuator exhibits remarkable deformation capability (210°/7 s) and an efficient self-repair ability under various stimuli, including thermal (60-160 °C), light (0.4-1.0 W·cm^-2), electric (2-4 V), and solvent (acetone). By adjustment of the orientation angle of CFs, complex left-handed and right-handed curling structures can be achieved. Leveraging the insights from photothermal/electrothermal actuation mechanisms, a quadruped crawling robot is developed capable of crawling 4 cm with a single light illumination. The actuator can lift objects 45 times its weight when subjected to light stimuli. Additionally, a flap actuator is constructed to achieve an angle change of 63° within 10 s under an electric stimulus, enabling remote control over the aircraft flight angle. These results demonstrate the potential of the vitrimer-CF actuator for advanced applications in intelligent aerospace structures.