Regulating self-assembly of concomitant isotropic Ag78 and anisotropic Ag110 nanoclusters
Two similar-sized Ag nanoclusters (NCs) with the same multiple-shell structure but different assembly trends (isotropic Ag 78 and anisotropic Ag 110 ) were prepared via a one-pot method. CF 3 COOAg-mediated directional intracluster self-assembly was employed to achieve NC separation, whereas acid-ligand exchange triggered the chiroptical response of Ag 110 , underscoring the pivotal role of small acids in the synthesis of Ag NCs.
Authors
- Shuang‐Quan Zang (ORCID: https://orcid.org/0000-0002-6728-0559)
- Shuo Huang (ORCID: https://orcid.org/0000-0002-3730-8485)
- Xi‐Ming Luo (ORCID: https://orcid.org/0000-0002-4999-9578)
- Xiaoyan Peng (ORCID: https://orcid.org/0009-0001-8340-1584)
- Jiahua Hu
- Haiyang Li (ORCID: https://orcid.org/0000-0002-6658-4745)
- Jia‐Hong Huang (ORCID: https://orcid.org/0000-0002-8610-2803)
- Yu-Jing Zhao (ORCID: https://orcid.org/0009-0001-8955-3546)
Institutions
- Zhengzhou University (CN)
Publication Details
- Journal
- Science Bulletin
- Published
- 2024-10-16
- DOI
- https://doi.org/10.1016/j.scib.2024.09.047
- Citations
- 6
- Primary Topic
- Nanocluster Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.70
Funders
- National Natural Science Foundation of China