New Insight into Quantity-Dependent Self-Assembly Pattern of Light Levitating Droplet Clusters

It has been reported that the self-assembly pattern of light levitating droplet clusters above the hot gas-liquid interface is dependent on the quantity of droplets. However, the already-reported theoretical explanation of the quantity-dependent self-assembly pattern cannot work well when the quantity of the light levitating droplet exceeds 15. Herein, we propose a new theoretical perspective to understand the self-assembly of a light levitating droplet cluster by referring to the classical densest packing problem of identical rigid circles in a larger circle with the introduction of the minimum total potential energy principle. Amazingly, the theoretical results obtained by this new approach agree well with experimental results, even though the quantity of the light levitating droplet is up to 142. This study deepens our understanding of the quantity-dependent self-assembly pattern of the light levitating droplet clusters and provides significant inspiration for other analogous self-assembly phenomena.

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Publication Details

Journal
The Journal of Physical Chemistry A
Published
2024-10-16
DOI
https://doi.org/10.1021/acs.jpca.4c06443
Primary Topic
Pickering emulsions and particle stabilization
Type
article
Field-Weighted Citation Impact
0.00

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article

New Insight into Quantity-Dependent Self-Assembly Pattern of Light Levitating Droplet Clusters

Pengcheng Jiang, Dingding Ye, Yijing Yang, Alexander A. Fedorets et al.
The Journal of Physical Chemistry A
Pickering emulsions and particle stabilization
article

New Insight into Quantity-Dependent Self-Assembly Pattern of Light Levitating Droplet Clusters

Pengcheng Jiang, Dingding Ye, Yijing Yang, Alexander A. Fedorets, Michael Nosonovsky, Liang An, Hong Wang, Yang Yang, Qiang Liao, Rong Chen, Xun Zhu
article en

Abstract

It has been reported that the self-assembly pattern of light levitating droplet clusters above the hot gas-liquid interface is dependent on the quantity of droplets. However, the already-reported theoretical explanation of the quantity-dependent self-assembly pattern cannot work well when the quantity of the light levitating droplet exceeds 15. Herein, we propose a new theoretical perspective to understand the self-assembly of a light levitating droplet cluster by referring to the classical densest packing problem of identical rigid circles in a larger circle with the introduction of the minimum total potential energy principle. Amazingly, the theoretical results obtained by this new approach agree well with experimental results, even though the quantity of the light levitating droplet is up to 142. This study deepens our understanding of the quantity-dependent self-assembly pattern of the light levitating droplet clusters and provides significant inspiration for other analogous self-assembly phenomena.

The Journal of Physical Chemistry AVol. 128(43)
Hong Kong Polytechnic University (HK), Chongqing University (CN), University of Tyumen (RU), Institute of Engineering Thermophysics (CN), University of Wisconsin–Milwaukee (US)
National Natural Science Foundation of China
Openalex Percentile: Top 89%
Pickering emulsions and particle stabilization
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