Optical parameters of PANI.CSA/PMMA nanofibers

Abstract Polyaniline doped with camphor sulphonic/Poly(methyl methacrylate) PANI.CSA/PMMA nanofibers were manufactured by electrospinning technology, where all parameters of the electrospinning system are fixed and the effect of the needle gauge on the properties of the prepared nanofibers is studied at different needle gauge (18, 20, 23 G). The polyaniline was manufactured by aniline-chemical oxidation polymerization. The nanofibers were diagnosed by an FE-SEM scanner to identify the surface morphology of the samples and the diameters of the nanofibers, it shows that nanofibers become more regular and their diameters become smaller as the diameter of the needle decreases. The samples were measured by the analysis of UV-visible spectroscopy, identifying the optical properties of the nanofibers and calculating the energy gap, which was valued ranging from 2.8 eV to 3.2 eV, increased due to the phenomenon of the quantitative restriction. Absorption coefficient and optical constants were also studied as a function of needle gauge.