Triplet Energy Gap‐Regulated Room Temperature Phosphorescence in Host–Guest Doped Systems

The organic room temperature phosphorescence (RTP) materials via host-guest doped method receive considerable attention in the fields of optoelectronics, bioimaging, and information encryption. Despite many host-guest doped materials with excellent RTP properties have been developed, their luminous mechanism is still limited. Here, a series of host-guest doped materials, using benzophenone as the host and quinone compounds as the guests, were constructed to investigate the effect of the triplet energy gap (ΔE_T) between the host and guest on triplet states population. The guest's triplet state is proposed to be a "triplet energy reservoir", gathering the triplet excitons to emit RTP when ΔE_T is large and returning triplet excitons to the host when ΔE_T is small. By combining the results of steady-state and delayed emission spectra, time-resolved transient absorption spectra, and theoretical calculations, a bidirectional energy transfer process is proved, which are triplet-triplet energy transfer and reverse triplet-triplet energy transfer processes. The thermal equilibrium of these two energy transfer processes can be regulated by the ΔE_T and temperature. The potential applications of these RTP properties are also realized in data encryption and anti-counterfeiting. This work provides valuable insight into the design of host-guest doped materials based on energy transfer mechanisms.