Increasing the Efficiency of Thermoelectric Conversion of Solar Energy

The article considers the latest achievements in the field of thermionic conversion of solar energy. The key aspects of thermionic emission, the problems of reducing the electrode work function and increasing the efficiency of devices are analyzed. It is shown that diamonds doped with phosphorus can be an attractive material for the purposes of thermionic emission. In this case, the presence of donor states can significantly narrow the space charge region, and at the same time reduce the potential barrier in the work function. The studies also found that the most successful and widely used method for overcoming the space charge effect is filling the interelectrode gap with cesium. The efficiency of thermionic conversion devices for solar energy increases by 1.6 times. Particular attention is paid to the use of new materials, such as nanostructures and carbon nanotubes, as well as promising technologies, such as photonic enhancement of thermionic processes. The analysis of the results showed that the photonic enhancement of the electron yield due to illumination is greater in p-type silicon, as predicted by theoretical models. The thermionic current increases by 1.7 times compared to silicon. The distance between the quasi-Fermi level and the Fermi level in n-type silicon is less than this distance in p-type silicon. As a consequence, the number of electrons in the conduction band is smaller. Methods for combating the space charge effect and optimizing the configuration of energy conversion systems are discussed.