Shadow Mask Molecular Beam Epitaxy for In‐Plane Gradient Permittivity Materials

Abstract Infrared spectroscopy currently requires the use of bulky, expensive, and/or fragile spectrometers. For gas sensing, environmental monitoring, or other applications, an inexpensive, compact, robust on‐chip spectrometer is needed. One way to achieve this is through gradient permittivity materials, in which the material permittivity changes as a function of position in the plane. Here, synthesis of infrared gradient permittivity materials is demonstrated using shadow mask molecular beam epitaxy. The permittivity of the material changes as a function of position in the lateral direction, confining varying wavelengths of infrared light at varying horizontal locations. An electric field enhancement corresponding to wavenumbers ranging from ≈650 to 900 cm −1 over an in‐plane width of ≈13 µm on the flat mesa of the sample is shown. An electric field enhancement corresponding to wavenumbers ranging from ≈900 to 1250 cm −1 over an in‐plane width of ≈13 µm on the slope of the sample is also shown. These two different regions of electric field enhancement develop on two opposite sides of the material. This demonstration of a scalable method of creating in‐plane gradient permittivity material can be leveraged for the creation of a variety of miniature infrared devices, such as an ultracompact spectrometer.