Multi-scale ceramic TiC solves the strength-plasticity equilibrium problem of high entropy alloy

• In this paper, ceramic particle reinforcement has been applied to Al 0.4 CoCrFe 2 Ni 2 high entropy alloys (FCC) to solve the problem of strength and plastic balance. • The multi-scale coupling of ceramic TiC reinforced high entropy alloy has obtained a novel network structure, with TiC (μm) in the interdendrites and TiC (nm) distributed in the crystals uniformly. • The strength of the alloy is improved by deftly and fully use of the second phase strengthening, including the dislocation cutting strengthening and dislocation bypass strengthening mechanism caused by ceramic TiC. • The introduction of nano-reinforced phase TiC further improves the strength of the alloy, provides more dislocation nucleation sources, and improves the plastic deformation ability of the alloy. High entropy alloys (HEAs) with single FCC structure exhibits unique structure and properties. However, lack of strength hinds the engineering application ability seriously. Therefore, it is urgent to propose effective methods and theories to enhance the strength while maintaining favorable plasticity. Introducing reinforced phases is one crucial research approach for improving the mechanical properties of HEAs. However, the resulting reduction in ductility has been neglected. In this work, we propose a novel multi-scale TiC coupling reinforced alloy which preserves the high plasticity while increasing the strength. The results demonstrate that TiC (μm) hinders the dislocations movement and improves strength through the second phase strengthening mechanism. Apart from acting as barriers to dislocation motion, the TiC (nm) also provides more dislocation sources in the distortion area at the junction with the matrix, which increasing the number of movable dislocations and enhancing the plastic strain capacity. Compared with the Al 0.4 alloy, the tensile yield strength of the Al 0.4 -TiC (μm + nm) alloy is increased by 145 %, the ultimate tensile strength is up to 574 MPa, while maintaining a high plastic strain by 30.1 %. The addition of multi-scale ceramic phase TiC provides a novel approach to obtain high strength and high plasticity HEAs.

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Publication Details

Journal
Materials & Design
Published
2024-10-12
DOI
https://doi.org/10.1016/j.matdes.2024.113374
Citations
5
Primary Topic
High Entropy Alloys Studies
Type
article
Field-Weighted Citation Impact
1.06
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Multi-scale ceramic TiC solves the strength-plasticity equilibrium problem of high entropy alloy

Chenghao Liu, Siruo Zhang, Hao Qi, Guanglong Li et al.
5 citations
Materials & Design
High Entropy Alloys Studies
1.06
article

Multi-scale ceramic TiC solves the strength-plasticity equilibrium problem of high entropy alloy

Chenghao Liu, Siruo Zhang, Hao Qi, Guanglong Li, Rongde Li, Yingdong Qu, Shulin Dong
article en
5 citations

Abstract

• In this paper, ceramic particle reinforcement has been applied to Al 0.4 CoCrFe 2 Ni 2 high entropy alloys (FCC) to solve the problem of strength and plastic balance. • The multi-scale coupling of ceramic TiC reinforced high entropy alloy has obtained a novel network structure, with TiC (μm) in the interdendrites and TiC (nm) distributed in the crystals uniformly. • The strength of the alloy is improved by deftly and fully use of the second phase strengthening, including the dislocation cutting strengthening and dislocation bypass strengthening mechanism caused by ceramic TiC. • The introduction of nano-reinforced phase TiC further improves the strength of the alloy, provides more dislocation nucleation sources, and improves the plastic deformation ability of the alloy. High entropy alloys (HEAs) with single FCC structure exhibits unique structure and properties. However, lack of strength hinds the engineering application ability seriously. Therefore, it is urgent to propose effective methods and theories to enhance the strength while maintaining favorable plasticity. Introducing reinforced phases is one crucial research approach for improving the mechanical properties of HEAs. However, the resulting reduction in ductility has been neglected. In this work, we propose a novel multi-scale TiC coupling reinforced alloy which preserves the high plasticity while increasing the strength. The results demonstrate that TiC (μm) hinders the dislocations movement and improves strength through the second phase strengthening mechanism. Apart from acting as barriers to dislocation motion, the TiC (nm) also provides more dislocation sources in the distortion area at the junction with the matrix, which increasing the number of movable dislocations and enhancing the plastic strain capacity. Compared with the Al 0.4 alloy, the tensile yield strength of the Al 0.4 -TiC (μm + nm) alloy is increased by 145 %, the ultimate tensile strength is up to 574 MPa, while maintaining a high plastic strain by 30.1 %. The addition of multi-scale ceramic phase TiC provides a novel approach to obtain high strength and high plasticity HEAs.

Materials & DesignVol. 247
Shenyang University of Technology (CN), Key Laboratory for High Strength Lightweight Metallic Materials of Shandong Province (CN)
Openalex Percentile: Top 26%
High Entropy Alloys Studies
1.06
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