Orientation-dependent deformation and failure of micropillar shape memory ceramics: A 3D phase-field study

Some microscopic samples of zirconia-based shape memory ceramics (SMCs) have shown full martensitic phase transformation (MPT) over multiple loading cycles without cracking. However, the occurrence of MPT is strongly influenced by grain orientation. Depending on the specific grain orientation relative to the loading direction, alternative mechanisms such as plastic slip and fracture may emerge. This study introduces a phase-field (PF) based framework that integrates a PF-MPT model, a PF fracture model, and a crystal viscoplasticity model to investigate the effects of grain orientation on MPT, plastic slip, and fracture mechanisms in SMC micropillars. Single crystal micropillars are created to distinguish the orientations that facilitate each mechanism. A wide range of grain orientations are found to predominantly exhibit MPT. Micropillars with grain orientations close to the (100) and (001) directions primarily experience fracture, with minimal plastic slip. Additionally, samples oriented along the (110) direction show a significant amount of plastic slip. A pole figure is constructed to elucidate the interplay between MPT, cracking, and slip under compressive loading conditions. This research provides valuable insights into the intricate behavior of SMCs under different loading scenarios, crucial for optimizing their performance in practical applications.