Solid-State Fluorescent Carbon Dots with Hydrophobic Modification Induced Red Emission for White Light-Emitting Diodes

Herein, we developed red solid-state fluorescent carbon dots (SSF-CDs) through a one-step solvothermal method, utilizing acetone as the carbonization solvent. Optical and structural characterization revealed that the sp² domains in the core of the R-CDs were consistently interrupted and that the oxygen-containing groups on the surface were replaced by alkyl groups. This substitution mitigates excessive π-π interactions, thereby preventing quenching of fluorescence in the solid state. Adjusting the molar ratio of citric acid (CA) and urea yielded solid fluorescent carbon dots (CDs) with panchromatic luminescence, indicating enhanced π-π interactions and more pronounced red shifts in the emission peaks. Furthermore, we found that this strategy is applicable to other carbon sources, including phenylenediamine, salicylic acid, and lignin. This research presents an innovative strategy for the fabrication of solid-state luminescent CDs.