Allylation of aldehydes with various allylation agents

• This article focuses on recent studies, but also includes studies from 2001. • Specific methods have not been selected for review, but the latest achievements have been reviewed with different methods. • Allyl acetate, allyl trichlorosilane, allyltributyltin, allylbromides, allylchlorides, cyclic allylic halides, and allylboronic acid pinacol ester were investigated as allylation agents. Allylation of aldehydes is one of the most important organic transformations that helps in the synthesis of compounds with special skeletons with unique medicinal properties. From 2001 to 2024, extensive research has been done in this field using different catalysts, and this organic technology is maturing. Most of the studies are based on the use of different catalysts and various ligands to obtain maximum diastereoselectivity and enantioselectivity. In this review, we have summarized recent research on the allylation of aldehydes using various allylation agents, including allyl acetate, allyl trichlorosilane, allyltributyltin, allylbromides, allylchlorides, cyclic allylic halides, and allylboronic acid pinacol ester. Additionally, we have reviewed studies from 2001 to the present. The primary focus of this review is the overall progress in this field.

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Publication Details

Journal
Results in Chemistry
Published
2024-10-01
DOI
https://doi.org/10.1016/j.rechem.2024.101847
Citations
7
Primary Topic
Asymmetric Synthesis and Catalysis
Type
article
Field-Weighted Citation Impact
1.75

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article

Allylation of aldehydes with various allylation agents

Yavar Ahmadi
7 citations
Results in Chemistry
Asymmetric Synthesis and Catalysis
1.75
article

Allylation of aldehydes with various allylation agents

Yavar Ahmadi
article en
7 citations

Abstract

• This article focuses on recent studies, but also includes studies from 2001. • Specific methods have not been selected for review, but the latest achievements have been reviewed with different methods. • Allyl acetate, allyl trichlorosilane, allyltributyltin, allylbromides, allylchlorides, cyclic allylic halides, and allylboronic acid pinacol ester were investigated as allylation agents. Allylation of aldehydes is one of the most important organic transformations that helps in the synthesis of compounds with special skeletons with unique medicinal properties. From 2001 to 2024, extensive research has been done in this field using different catalysts, and this organic technology is maturing. Most of the studies are based on the use of different catalysts and various ligands to obtain maximum diastereoselectivity and enantioselectivity. In this review, we have summarized recent research on the allylation of aldehydes using various allylation agents, including allyl acetate, allyl trichlorosilane, allyltributyltin, allylbromides, allylchlorides, cyclic allylic halides, and allylboronic acid pinacol ester. Additionally, we have reviewed studies from 2001 to the present. The primary focus of this review is the overall progress in this field.

Results in ChemistryVol. 11
Farhangian University (IR)
Farhangian University
Openalex Percentile: Top 16%
Asymmetric Synthesis and Catalysis
1.75
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Allylation of aldehydes with various allylation agents — Yavar Ahmadi · Results in Chemistry (2024) | TGRS Research Map | TGRS