Dehydration by Pervaporation of an Organic Solution for the Direct Synthesis of Diethyl Carbonate

Pervaporation has been a central subject in the research community within the scope of the further development of energy- and cost-efficient alternatives to conventional liquid–liquid separation technologies. The potential eligibility of four commercial membranes (ZEBREX ZX0, PERVAPTM 4155-80, PERVAPTM 4100, PERVAPTM 4101) for use in an integrated dehydration application of a diethyl carbonate/water/ethanol mixture by pervaporation was assessed experimentally. The impact of feed concentration, operating temperature, pressure, and sweep gas flow rate on membrane separation performance, including permeation flux, permeate quality, selectivity, and permeance, was thoroughly investigated. Applying the ZX0 membrane delivered the best qualities of all tested membranes of the permeate stream, with a water concentration of mostly >98%. In comparing the water flux, the ZX0 membrane remained reasonably competitive with the polymer membranes. Furthermore, the sweep gas volume flow rate and the operating temperature were identified as influencing the flux significantly but not the product composition. At the same time, the feed concentration of water also influenced the water purity within the permeate. The experiments were monitored with a partial least squares model, allowing a quick assessment of obtained samples while delivering accurate results.