One-Pot Synthesis of Heptanuclear Gold Cluster [Au7(Ph3P)7@C]2+ in the Presence of the Macropolyhedral Octadecahydroeicosaborate Anion [B20H18]2–
The reaction between [Au(Ph3P)Cl] and [B20H18]2– in DMF gave unprecedented heptanuclear cationic gold cluster [Au7(Ph3P)7@C]2+ isolated as [Au7(Ph3P)7@C][B20H18][Au(Ph3P)Cl]·0.5DMF in one step. The final compound was studied by 11B NMR and IR spectroscopies, ESI MS, single-crystal and powder X-ray diffractions. No special reagents were used to obtain central carbon atom in the cluster [Au7(Ph3P)7@C]2+.
Authors
- Varvara Vladimirovna Avdeeva (ORCID: https://orcid.org/0000-0002-0655-1052)
- Г. А. Бузанов (ORCID: https://orcid.org/0000-0003-2676-8774)
- Анна В. Вологжанина (ORCID: https://orcid.org/0000-0002-6228-303X)
- Valentin V. Novikov (ORCID: https://orcid.org/0000-0002-0225-0594)
- Nikolay T. Kuznetsov (ORCID: https://orcid.org/0000-0002-0131-6387)
- E. A. Malinina
Institutions
- A. N. Nesmeyanov Institute of Organoelement Compounds (RU)
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
- Universitat de Barcelona (ES)
Publication Details
- Journal
- Russian Journal of Inorganic Chemistry
- Published
- 2024-10-10
- DOI
- https://doi.org/10.1134/s0036023624602605
- Citations
- 1
- Primary Topic
- Boron Compounds in Chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.40