Silver Nanowire Aerogel Support Promotes Stable Hydrogen Evolution Reaction at High Current Density

The stability of electrocatalysts during the hydrogen evolution reaction (HER) is vital for efficient production of hydrogen energy. Herein, we demonstrate that silver nanowire aerogel-based support (AABS) could facilitate the construction of HER catalysts with extraordinary long-term stability. A full nanostructure catalyst of nickel phosphide based formed on AABS (Ni₂P-Ni₅P₄@AABS) was prepared to achieve an overpotential of 687 mV (without <i>iR</i> compensation) for HER at the current density of 1 A cm^-2 in 0.5 M H₂SO₄. Excitingly, the stable HER performance was kept for 42 days during the long-term stability (i-t) test at high current density (0.5-1 A cm^-2). The excellent HER performance of the Ni₂P-Ni₅P₄@AABS catalyst is attributed to rapid electron transport pathways, numerous more accessible active sites, and support induced enhanced catalytic activity. The support effect was highlighted by a proposed phenomenological two-channel model for electron transport, which provides fresh insights into the design strategy for energy storage and delivery.