DMSO/SOCl<sub>2</sub>‐Mediated Synthesis of Thiomethylnaphthalenes from Propargyl Alcohols
Abstract Herein, we reported the straightforward synthesis of thiomethylnaphthalenes via the reaction of propargyl alcohols with dimethyl sulfoxide/thionyl chloride (DMSO/SOCl 2 ), which also provided easy access to deuterated thiomethyl and other thioalkyl scaffolds when deuterated dimethyl sulfoxide and dialkyl sulfoxides were used, respectively. In addition, the thiomethyl group can be readily derivatized to the corresponding sulfoxide, sulfone, and sulfoximine of interesting photophysical properties.
Authors
- Ke‐Yin Ye (ORCID: https://orcid.org/0000-0003-3955-7079)
- Xinglei He
- Wang‐Fu Liang
- Zhihua Wang (ORCID: https://orcid.org/0000-0002-7521-2900)
- J. Li (ORCID: https://orcid.org/0009-0004-9448-7303)
Institutions
- Henan Normal University (CN)
- Fuzhou University (CN)
Publication Details
- Journal
- Advanced Synthesis & Catalysis
- Published
- 2024-10-08
- DOI
- https://doi.org/10.1002/adsc.202401025
- Citations
- 5
- Primary Topic
- Sulfur-Based Synthesis Techniques
- Type
- article
- Field-Weighted Citation Impact
- 1.25
Funders
- Henan Normal University
- National Natural Science Foundation of China