Canna edulis ker. starch-based biodegradable plastic materials: mechanical and morphological properties

Bioplastics were produced by mixing starch with sorbitol, glacial acetic acid, and carboxymethyl cellulose (CMC) during the manufacturing process. The physical characteristics of the bioplastics were investigated using Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Tensile strength, elongation, and Young’s modulus tests were utilized to assess the mechanical characteristics of bioplastics. The bioplastic with the highest tensile strength was BP3 (7.03 ± 0.34 N/mm2), whereas BP0 had a tensile strength of 1.57 ± 0.11 N/m2. The addition of CMC increased the viscosity of the solution and, consequently, the strength of the bioplastic. The range of bioplastic hydrophobicity was ~ 128.32–323.74%. FTIR and XPS test results indicated that the physical mixing utilized during synthesis did not result in the addition of functional groups other than the native functional groups of the substances since no chemical reaction occurred. The thermal behavior investigation revealed that increasing the amount of CMC added to TPS can increase the presence of O–H functional groups in bioplastics, contributing to an increase in the glass transition temperature. Furthermore, both bioplastics broke down at ~ 250 °C.

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Publication Details

Journal
Discover Materials
Published
2024-10-08
DOI
https://doi.org/10.1007/s43939-024-00128-z
Citations
4
Primary Topic
biodegradable polymer synthesis and properties
Type
article
Field-Weighted Citation Impact
0.69

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article

Canna edulis ker. starch-based biodegradable plastic materials: mechanical and morphological properties

Abdul Halim, Toshiharu Enomae, Yunita Sasmi Taradipa, Kotchaporn Thangunpai et al.
4 citations
Discover Materials
biodegradable polymer synthesis and properties
0.69
article

Canna edulis ker. starch-based biodegradable plastic materials: mechanical and morphological properties

Abdul Halim, Toshiharu Enomae, Yunita Sasmi Taradipa, Kotchaporn Thangunpai, R. M. Muhammad Nur Fauzan, Surya Iryana Ihsanpuro, Alifia Yuanika Rahmawati, Azmi Alvian Gabriel, Sazkia Indramawarni
article en
4 citations

Abstract

Bioplastics were produced by mixing starch with sorbitol, glacial acetic acid, and carboxymethyl cellulose (CMC) during the manufacturing process. The physical characteristics of the bioplastics were investigated using Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential scanning calorimetry (DSC). Tensile strength, elongation, and Young’s modulus tests were utilized to assess the mechanical characteristics of bioplastics. The bioplastic with the highest tensile strength was BP3 (7.03 ± 0.34 N/mm2), whereas BP0 had a tensile strength of 1.57 ± 0.11 N/m2. The addition of CMC increased the viscosity of the solution and, consequently, the strength of the bioplastic. The range of bioplastic hydrophobicity was ~ 128.32–323.74%. FTIR and XPS test results indicated that the physical mixing utilized during synthesis did not result in the addition of functional groups other than the native functional groups of the substances since no chemical reaction occurred. The thermal behavior investigation revealed that increasing the amount of CMC added to TPS can increase the presence of O–H functional groups in bioplastics, contributing to an increase in the glass transition temperature. Furthermore, both bioplastics broke down at ~ 250 °C.

Discover MaterialsVol. 4(1)
University of Tsukuba (JP), Universitas Internasional Semen Indonesia (ID)
Kementerian Riset dan Teknologi /Badan Riset dan Inovasi Nasional, Japan Society for the Promotion of Science
Openalex Percentile: Top 34%
biodegradable polymer synthesis and properties
0.69
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