Atomic-Scale Mechanism of Enhanced Electron–Phonon Coupling at the Interface of MgB₂ Thin Films

In conventional Bardeen-Cooper-Schrieffer (BCS) superconductors, electron-phonon coupling is the fundamental mechanism of superconductivity. For instance, the superconductivity of magnesium diboride (MgB₂) comes from the coupling between <i>E</i>_<i>2g</i> modes (in-plane boron-boron bond vibrations) and self-doped charge carriers. In thin films and ceramics of BCS superconductors, interfaces with discontinuous chemical bonds may alter the local electron-phonon coupling. However, such effects remain largely unexplored. Here, we investigate the heterointerface of the MgB₂ film on the SiC substrate at the atomic scale using electron microscopy and spectroscopy. We detect the presence of a thin MgO layer with a thickness of ∼1 nm between MgB₂ and SiC. Atomic-level electron energy loss spectra (EELS) show MgB₂-<i>E</i>_<i>2g</i> mode splitting and softening near the MgB₂/MgO interface, which enhances electron-phonon coupling at the interface. Our findings highlight the potential of interface engineering to enhance superconductivity via modulating local phonon states and/or electron states.