Methyl 2-[(<i>Z</i>)-5-methyl-2-oxoindolin-3-ylidene]hydrazinecarbodithioate
The title di-thio-carbazate imine, C<sub>11</sub>H<sub>11</sub>N<sub>3</sub>OS<sub>2</sub>, was obtained from the condensation reaction of <i>S</i>-methyl-dithio-carbazate (SMDTC) and 5-methyl-isatin. It shows a <i>Z</i> configuration about the imine C=N bond, which is associated with an intra-molecular N-H⋯O hydrogen bond that closes an <i>S</i>(6) ring. In the crystal, inversion dimers linked by pairwise N-H⋯O hydrogen bonds generate <i>R</i> <sup>2</sup> <sub>2</sub>(8) loops. The extended structure features C-H⋯S contacts as well as reciprocal carbon-yl-carbonyl (C=O⋯C=O) inter-actions.
Authors
- David B. Cordes (ORCID: https://orcid.org/0000-0002-5366-9168)
- Aidan P. McKay (ORCID: https://orcid.org/0000-0002-8578-7054)
- Mohd Abdul Fatah Abdul Manan (ORCID: https://orcid.org/0000-0001-9992-0306)
Institutions
- University of St Andrews (GB)
- Universiti Teknologi MARA (MY)
Publication Details
- Journal
- IUCrData
- Published
- 2024-10-08
- DOI
- https://doi.org/10.1107/s2414314624009672
- Primary Topic
- Synthesis and biological activity
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- Universiti Teknologi MARA