Synthesis and crystal structure of sodium (ethane-1,2-diyl)bis[(3-methoxypropyl)phosphinodithiolate] octahydrate
The title compound, <i>catena</i>-poly[[tri-aqua-sodium]-di-μ-aqua-[tri-aqua-sodium]-μ-(ethane-1,2-di-yl)bis-[(3-meth-oxy-prop-yl)phosphinodi-thiol-ato]], [Na<sub>2</sub>(C<sub>10</sub>H<sub>22</sub>O<sub>2</sub>P<sub>2</sub>S<sub>4</sub>)(H<sub>2</sub>O)<sub>8</sub>] <sub><i>n</i></sub> , crystallizes in the triclinic space group <i>P</i>1. The dianionic [CH<sub>3</sub>O(CH<sub>2</sub>)<sub>3</sub>P(=S)(S-)CH<sub>2</sub>CH<sub>2</sub>P(=S)(S-)(CH<sub>2</sub>)<sub>3</sub>OCH<sub>3</sub>]<sup>2-</sup> ligand fragments are joined by a dicationic [Na<sub>2</sub>(H<sub>2</sub>O)<sub>8</sub>]<sup>2+</sup> cluster that includes the oxygen of the meth-oxy-propyl unit of the ligand to form infinite chains.
Authors
- David R. Tyler (ORCID: https://orcid.org/0000-0002-5032-7533)
- Dean H. Johnston (ORCID: https://orcid.org/0000-0001-7533-8178)
- Lev N. Zakharov (ORCID: https://orcid.org/0000-0002-8680-3474)
- Bryan P. Nell (ORCID: https://orcid.org/0000-0002-4694-8361)
Institutions
- University of Oregon (US)
- Otterbein University (US)
- Ripon College (US)
Publication Details
- Journal
- Acta Crystallographica Section E Crystallographic Communications
- Published
- 2024-10-08
- DOI
- https://doi.org/10.1107/s2056989024009642
- Primary Topic
- Crystal structures of chemical compounds
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- National Science Foundation
- Directorate for Mathematical and Physical Sciences